五元体系Li~ /Cl~-,CO_3~(2-),SO_4~(2-),B_4O_7~(2-)-H_2O298K相关系实验研究

青藏高原盐湖富含锂、钠、钾的氯化物、硫酸盐、碳酸盐和硼酸盐,尤以其高锂、硼而闻名于世[1]。这些盐湖卤水大多属于Li ,Na ,K ,Mg2 /Cl-,SO42-,CO32-,Borate-H2O体系。在卤水蒸发浓缩后期,由于绝大部分钠盐、钾盐均已结晶析出,所以卤水的化学组成实际变成Li ,Mg2 /Cl-,SO42-,     

北京自由电子激光最近进展──实现饱和振荡

北京自由电子激光(BFEL)装置于1993年底在10.68μm处实现了饱和振荡.输出激光能量为3mJ,饱和平顶宽度2μs.对应饱和振荡平均功率为210kW(宏脉冲),峰值功率约为20MW,比自发辐射高8个量级,单程小讯号净增益为24%,转换效率为0.45%,与理论预期结果相符.光束质量接近衍射极限.目前装置可工作于9-11μm.     

Syntheses and Structures of Sil abridged Hafnocene Dichlorides

The present paper covers three silabridged hafnocene dichlorides(1, 2 and 3) prepared by sequential reactions of α, ω-dichloropermethyl polysilane with cyclopentadienyl sodium, n-butyl lithium and hafnium tetrachloride. Their structures were characterized by elemental analyses, UV, 1H(13C) NMR and MS. Furthermore the crystal and molecular structures of 1 and 2 were determined by X-ray diffraction method. The crystal of 1 is monoclinic, space group C2/c with a=1. 3401(4), b=0. 9977(3), c = 1. 0922(4) nm; β=94. 07(1)° V=3. 6342 nm3, Z = 2, Dc = 2.155 g·cm-3. The final deviation factor R = 0. 064. The crystal of 2 is monoclinic, space group P21/c with a=0.0847(1), b=1.5181(1), c=2.9824(2) nm; β= 94. 07(1)°? V=3.634 nm3; Dc= l. 805 g·cm-3. The final deviation factor R = 0. 033. The relationship between the silabridged structure and spectral properties is also discussed.     

布尔“复合函数”的Walsh循环谱和自相关函数

本文利用布尔随机变量联合分布的分解式给出了布尔“复合函数”和某布尔函数符合率的分解算式,由此求得了布尔“复合函数”的 Walsh循环谱和自相关函数的计算公式,公式清楚地表明了“复合”所得布尔函数的 Walsh循环谱与起“复合”作用的函数和被“复合”的各函数所有线性组合的 Walsh循环谱之间的关系、“复合”所得布尔函数的自相关函数与起“复合”作用的函数谱和被“复合”的各函数的谱及相关函数之间的关系,这两个公式在布尔函数的密码学性质研究中会有广泛的应用.     

Navier-Stokes方程带Backtracking技巧的两重网格算法

1 引 言考虑二维不可压 Navier-Stokes方程:     

传输线中脉冲信号反射波的测量和应用

将高频单脉冲信号输入同轴电缆，借助数字存储示波器记录输入、输出端的波形和相对延时，可以测量传输线的电缆长度和衰减系数，同时观察脉冲波形因色散引起的畸变．     

一个在水稻胚胎中差异表达基因的分离鉴定

通过筛选水稻开花后48～50h的原胚和120～122h的分化胚的cDNA文库,得到一个在胚胎发育过程中表达有差异的克隆,命名为OsEES,测序结果显示OsEES含有一个预测的亚精氨合成酶结构域,编码一个大小约38×103(pI6.5)的蛋白.同时RNA原位杂交的结果显示开花48～50h的原胚中的信号强度明显大于开花120～122h的分化胚,表明OsEES可能在水稻胚胎发生过程中起到一定的调控作用.     

Melt rheology of polylactide/montmorillonite nanocomposites

In this article, the linear and nonlinear shear rheological behaviors of polylactide (PLA)/clay (organophilic‐montmorillonite) nanocomposites (PLACNs) were investigated by an Advanced Rheology Expanded System rheometer. The nanocomposites were prepared by master batch method using a twin‐screw extruder with poly(ε‐caprolactone) (PCL) as a compatibilizer. The presence of org‐MMT leads to obvious pseudo‐solid‐like behaviors of nanocomposite melts. The behaviors caused by the formation of a “percolating network” derived from the reciprocity among the strong related sheet particles. Therefore, the storage moduli, loss moduli, and dynamic viscosities of PLACNs show a monotonic increase with MMT content. Nonterminal behaviors exists in PLACNs nanocomposites. Besides the PLACNs melts show a greater shear thinning tendency than pure PLA melt because of the preferential orientation of the MMT layers. Therefore, PLACNs have higher moduli but better processibility compared with pure PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3189–3196, 2007     

光学扫描全息术中的孪生像噪音及消除

阐述了光学扫描全息术的基本原理,分析了孪生像噪音的来源,提出了一种新的数字滤波方法.计算机仿真结果表明:孪生像噪音以振荡形式传播,降低了重构图像的信噪比,影响了重构图像的分辨率;用电子复用技术,即用复全息图函数代替实全息图函数的方法可以有效地消除孪生像噪音;采用单一通道对信号进行处理,即只用一个实全息图函数,通过数字滤波方法同样可以消除孪生像噪音,该方法简便、实用而有效.     

Preparation,thermal properties,and flame retardance of epoxy–silica hybrid resins

A novel epoxy system was developed through the in situ curing of bisphenol A type epoxy and 4,4′‐diaminodiphenylmethane with the sol–gel reaction of a phosphorus‐containing trimethoxysilane (DOPO–GPTMS), which was prepared from the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) with 3‐glycidoxypropyltrimethoxysilane (GPTMS). The preparation of DOPO–GPTMS was confirmed with Fourier transform infrared, ¹H and ³¹P NMR, and elemental analysis. The resulting organic–inorganic hybrid epoxy resins exhibited a high glass‐transition temperature (167 °C), good thermal stability over 320 °C, and a high limited oxygen index of 28.5. The synergism of phosphorus and silicon on flame retardance was observed. Moreover, the kinetics of the thermal oxidative degradation of the hybrid epoxy resins were studied. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2354–2367, 2003